Volume 1. Structure and Dynamics of Membranes

Chapter 12. Electrostatic properties of membranes: The Poisson-Boltzmann theory

D. Andelman
School of Physics and Astronomy, Tel Aviv University,
Ramat Aviv 69978, Tel Aviv, Israel

1. Introduction

2. Charged surfaces in liquids: general considerations

2.1. Poisson-Boltzmann equation
2.2. Electrostatic free energy and electrostatic pressure
2.3. Beyond Poisson-Boltzmann: recent theory and experiment
3. A single flat and charged membrane
3.1. No added electrolyte
3.2. Added electrolyte
4. Two flat charged membranes
4.1. No added electrolyte
4.2. Added electrolyte
5. Flexible and charged membranes: general considerations

6. A single charged and flexible membrane

6.1. Electrostatic boundary conditions for bilayer membranes
6.2. One curved (spherical or cylindrical) charged membrane
6.3. One undulating membrane
6.4. Membranes with variable surface charge density
7. A stack of charged lamellae
7.1. Suppression of Helfrich interactions by electrostatics
7.2. Rigidity of charged lamellae
8. Conclusions and future prospects

Acknowledgments

References